四氯合铁(III)酸四乙基铵

四氯合铁(III)酸四乙基铵
识别
CAS号	14240-75-6
PubChem	15772697
ChemSpider	77429304
SMILES	CC[N+](CC)(CC)CC.[Cl-].Cl[Fe](Cl)Cl;
性质
化学式	C8H20Cl4FeN
摩尔质量	327.91 g·mol−1
外观	黄色粉末
密度	1.358 g/cm3
熔点	538 K
沸点	563 K（分解）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

四氯合铁(III)酸四乙基铵是一种配位化合物，化学式为(N(C₂H₅)₄)FeCl₄，或简写为(Et₄N)FeCl₄。它可由四乙基氯化铵和三氯化铁在乙醇中反应得到，它在四氢呋喃中可以结晶。^[3](Et₄N)₂[Fe₂S₂Cl₄]和氯化氢反应，也能得到该化合物。^[1]它和硝酸银在dppa存在下反应，可以得到[Ag₃(μ-Cl)(μ₃-Cl)(μ-dppa)₃][FeCl₄]。^[4]

参考文献[编辑]

^ ^1.0 ^1.1 Camly T. Tran, Eunsuk Kim. Acid-Dependent Degradation of a [2Fe–2S] Cluster by Nitric Oxide. Inorganic Chemistry. 2012-10-01, 51 (19): 10086–10088 [2022-11-12]. ISSN 0020-1669. doi:10.1021/ic301676f. （原始内容存档于2022-11-12）（英语）.
^ ^2.0 ^2.1 D. Wyrzykowski, Agnieszka Pattek-Janczyk, T. Maniecki, Katarzyna Zaremba, Z. Warnke. Thermal properties of tetraethylammonium tetrachloro-, bromotrichloro-and tribromochloroferrates(III). Journal of Thermal Analysis and Calorimetry. 2008-01, 91 (1): 279–284 [2022-11-12]. ISSN 1388-6150. doi:10.1007/s10973-006-8269-8 （英语）.
^ Martin Lutz, Yuxing Huang, Marc-Etienne Moret, Robertus J. M. Klein Gebbink. Phase transitions and twinned low-temperature structures of tetraethylammonium tetrachloridoferrate(III). Acta Crystallographica Section C Structural Chemistry. 2014-05-01, 70 (5): 470–476 [2022-11-12]. ISSN 2053-2296. doi:10.1107/S2053229614007955. （原始内容存档于2022-11-12）.
^ Hua-Tian Shi, Taike Duan, Chao Xu, Qian-Feng Zhang. Syntheses and Structures of Trinuclear Trigonal-bipyramidal Silver(I) Complexes with Bis(diphenylphosphino)amide Ligands. Zeitschrift für Naturforschung B. 2009-02-01, 64 (2): 204–208 [2022-11-12]. ISSN 1865-7117. doi:10.1515/znb-2009-0210. （原始内容存档于2022-11-12）（英语）.

[ic-1] 1.0 ^1.1 Camly T. Tran, Eunsuk Kim. Acid-Dependent Degradation of a [2Fe–2S] Cluster by Nitric Oxide. Inorganic Chemistry. 2012-10-01, 51 (19): 10086–10088 [2022-11-12]. ISSN 0020-1669. doi:10.1021/ic301676f. （原始内容存档于2022-11-12）（英语）.

[thermal-2] 2.0 ^2.1 D. Wyrzykowski, Agnieszka Pattek-Janczyk, T. Maniecki, Katarzyna Zaremba, Z. Warnke. Thermal properties of tetraethylammonium tetrachloro-, bromotrichloro-and tribromochloroferrates(III). Journal of Thermal Analysis and Calorimetry. 2008-01, 91 (1): 279–284 [2022-11-12]. ISSN 1388-6150. doi:10.1007/s10973-006-8269-8 （英语）.

[3] Martin Lutz, Yuxing Huang, Marc-Etienne Moret, Robertus J. M. Klein Gebbink. Phase transitions and twinned low-temperature structures of tetraethylammonium tetrachloridoferrate(III). Acta Crystallographica Section C Structural Chemistry. 2014-05-01, 70 (5): 470–476 [2022-11-12]. ISSN 2053-2296. doi:10.1107/S2053229614007955. （原始内容存档于2022-11-12）.

[4] Hua-Tian Shi, Taike Duan, Chao Xu, Qian-Feng Zhang. Syntheses and Structures of Trinuclear Trigonal-bipyramidal Silver(I) Complexes with Bis(diphenylphosphino)amide Ligands. Zeitschrift für Naturforschung B. 2009-02-01, 64 (2): 204–208 [2022-11-12]. ISSN 1865-7117. doi:10.1515/znb-2009-0210. （原始内容存档于2022-11-12）（英语）.

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