环臭氧

环臭氧
	系统名; Trioxirane
识别
CAS号	153851-84-4
PubChem	16206854
ChemSpider	13375217
SMILES	O1OO1;
InChI	1S/O3/c1-2-3-1;
InChIKey	XQOAKYYZMDCSIA-UHFFFAOYSA-N
性质
化学式	O3
摩尔质量	48 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

环臭氧是一种假设的氧的同素异形体，其与臭氧分子一样有三颗氧原子，但并非角型而是成环状。

简介[编辑]

直到目前，不同的理论研究已确定环臭氧存在的可能。^[2]^[3]^[4]另外也有实验指在1450℃以上在氧化镁的表面重构中识别出微量环臭氧。^[5]目前它并未能大量制造，而其中一个不成功的尝试是借助雷射。^[6]另一个被提出的可能办法是在一个加以限制的空间内使其稳定，例如富勒烯。^[3]

科学家对其特性有一些预测，如其标准摩尔生成焓比臭氧高130 kJ mol⁻¹，而它生成臭氧的活化能为95 kJ mol⁻¹。^[7]另外又有建议指，若果环臭氧能大量制造，且它较为稳定，便可加入液态氧中以增加火箭燃料的比冲量。^[6]

参考[编辑]

^ CID 16206854 - Compound Summary. PubChem Compound. USA: National Center for Biotechnology Information. Identification and Related Records. 11 July 2007 [21 October 2011]. （原始内容存档于2012-10-25）.
^ Xantheas, Sotiris; Atchity, Gregory; Elbert, Stephen; Ruedenberg, Klaus. Potential energy surfaces of ozone. I. J. Chem. Phys. 1991, 94 (12): 8054. Bibcode:1991JChPh..94.8054X. doi:10.1063/1.460140.
^ ^3.0 ^3.1 Sabirov, Denis; Igor, Shepelevich. Information entropy of oxygen allotropes. A still open discussion about the closed form of ozone. Computational and Theoretical Chemistry. 2015, 1073 (1): 61–66. doi:10.1016/j.comptc.2015.09.016.
^ Lee, Timothy. On the energy separation between the open and cyclic forms of ozone. Chemical Physics Letters. 1990, 169 (6): 529–533. Bibcode:1990CPL...169..529L. doi:10.1016/0009-2614(90)85642-P.
^ Plass, Richard; Kenneth Egan; Chris Collazo-Davila; Daniel Grozea; Eric Landree; Laurence D. Marks; Marija Gajdardziska-Josifovska. Cyclic Ozone Identified in Magnesium Oxide (111) Surface Reconstructions (PDF). Physical Review Letters. November 30, 1998, 81 (22): 4891–4894 [2010-06-05]. Bibcode:1998PhRvL..81.4891P. doi:10.1103/PhysRevLett.81.4891. （原始内容存档 (PDF)于2021-03-26）.
^ ^6.0 ^6.1 Temple Researcher Attempting To Create Cyclic Ozone. Science Daily. February 8, 2005 [2010-06-05]. （原始内容存档于2016-11-29）.
^ Hoffmann, Roald. The story of O. The Ring. American Scientist. January–February 2004, 92 (1): 23–24. doi:10.1511/2004.1.23.

[1] CID 16206854 - Compound Summary. PubChem Compound. USA: National Center for Biotechnology Information. Identification and Related Records. 11 July 2007 [21 October 2011]. （原始内容存档于2012-10-25）.

[2] Xantheas, Sotiris; Atchity, Gregory; Elbert, Stephen; Ruedenberg, Klaus. Potential energy surfaces of ozone. I. J. Chem. Phys. 1991, 94 (12): 8054. Bibcode:1991JChPh..94.8054X. doi:10.1063/1.460140.

[ReferenceA-3] 3.0 ^3.1 Sabirov, Denis; Igor, Shepelevich. Information entropy of oxygen allotropes. A still open discussion about the closed form of ozone. Computational and Theoretical Chemistry. 2015, 1073 (1): 61–66. doi:10.1016/j.comptc.2015.09.016.

[4] Lee, Timothy. On the energy separation between the open and cyclic forms of ozone. Chemical Physics Letters. 1990, 169 (6): 529–533. Bibcode:1990CPL...169..529L. doi:10.1016/0009-2614(90)85642-P.

[5] Plass, Richard; Kenneth Egan; Chris Collazo-Davila; Daniel Grozea; Eric Landree; Laurence D. Marks; Marija Gajdardziska-Josifovska. Cyclic Ozone Identified in Magnesium Oxide (111) Surface Reconstructions (PDF). Physical Review Letters. November 30, 1998, 81 (22): 4891–4894 [2010-06-05]. Bibcode:1998PhRvL..81.4891P. doi:10.1103/PhysRevLett.81.4891. （原始内容存档 (PDF)于2021-03-26）.

[sciencedaily-6] 6.0 ^6.1 Temple Researcher Attempting To Create Cyclic Ozone. Science Daily. February 8, 2005 [2010-06-05]. （原始内容存档于2016-11-29）.

[7] Hoffmann, Roald. The story of O. The Ring. American Scientist. January–February 2004, 92 (1): 23–24. doi:10.1511/2004.1.23.

[1]

[2]

[3]

[4]

[5]

[6]

[7]