疊氮化鍶

疊氮化鍶
英文名	strontium azide
識別
CAS號	19465-89-5
PubChem	57375454
SMILES	[N-]=[N+]=[N-].[N-]=[N+]=[N-].[Sr+2];
InChI	1S/2N3.Sr/c21-3-2;/q2-1;+2;
InChIKey	PDEROVFZLWBVSG-UHFFFAOYSA-N
性質
化學式	Sr(N3)2
摩爾質量	171.66 g·mol⁻¹
外觀	白色晶體粉末
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

疊氮化鍶是一種無機化合物，化學式為Sr(N₃)₂。它可由疊氮化氫和氫氧化鍶八水合物（或碳酸鍶^[1]）的反應製得。^[2]它在潮濕空氣中和二氧化碳反應生成碳酸鍶。^[3]它在含15-冠-5（[15]crown-5）的溶液中結晶，可以得到Sr([15]crown-5)(N₃)₂(H₂O)。^[4]它和五氮化三磷在高溫、高壓下反應，可以得到亞氨基氮代磷酸鍶（SrP₃N₅NH）。^[1]

參考文獻[編輯]

^ ^1.0 ^1.1 ^1.2 Sebastian Vogel, Wolfgang Schnick. SrP 3 N 5 NH: A Framework‐Type Imidonitridophosphate Featuring Structure‐Directing Hydrogen Bonds. Chemistry – A European Journal. 2018-09-20, 24 (53): 14275–14281 [2022-10-24]. ISSN 0947-6539. doi:10.1002/chem.201803210 （英語）.
^ Glen R. Kowach, N.E. Brese, U.M. Bolle, C.J. Warren, F.J. DiSalvo. An Unusual Metallic Nitride: Sr2NiN2. Journal of Solid State Chemistry. 2000-11, 154 (2): 542–550 [2022-10-24]. doi:10.1006/jssc.2000.8877. （原始內容存檔於2018-06-07）（英語）.
^ Ficheroulle, Henri; Kovache, Adolphe. Manufacture and testing of the azides of barium and strontium. Memorial des Poudres, 1951. 33: 7-19. ISSN 0369-1535.
^ Michael D. Brown, Martin F. Davis, John M. Dyke, Francesco Ferrante, William Levason, J. Steven Ogden, Michael Webster. Synthesis, Structures and DFT Calculations on Alkaline-Earth Metal Azide-Crown Ether Complexes. Chemistry - A European Journal. 2008-03-07, 14 (8): 2615–2624 [2022-10-24]. doi:10.1002/chem.200701502 （英語）.

[Vogel-1] 1.0 ^1.1 ^1.2 Sebastian Vogel, Wolfgang Schnick. SrP 3 N 5 NH: A Framework‐Type Imidonitridophosphate Featuring Structure‐Directing Hydrogen Bonds. Chemistry – A European Journal. 2018-09-20, 24 (53): 14275–14281 [2022-10-24]. ISSN 0947-6539. doi:10.1002/chem.201803210 （英語）.

[2] Glen R. Kowach, N.E. Brese, U.M. Bolle, C.J. Warren, F.J. DiSalvo. An Unusual Metallic Nitride: Sr2NiN2. Journal of Solid State Chemistry. 2000-11, 154 (2): 542–550 [2022-10-24]. doi:10.1006/jssc.2000.8877. （原始內容存檔於2018-06-07）（英語）.

[3] Ficheroulle, Henri; Kovache, Adolphe. Manufacture and testing of the azides of barium and strontium. Memorial des Poudres, 1951. 33: 7-19. ISSN 0369-1535.

[4] Michael D. Brown, Martin F. Davis, John M. Dyke, Francesco Ferrante, William Levason, J. Steven Ogden, Michael Webster. Synthesis, Structures and DFT Calculations on Alkaline-Earth Metal Azide-Crown Ether Complexes. Chemistry - A European Journal. 2008-03-07, 14 (8): 2615–2624 [2022-10-24]. doi:10.1002/chem.200701502 （英語）.

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