氯化三(2,2'-聯吡啶)合鐵(II)

氯化三(2,2'-聯吡啶)合鐵(II)
識別
CAS號	14751-83-8
PubChem	203609
ChemSpider	176367
SMILES	C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.[Cl-].[Cl-].[Fe+2];
性質
化學式	C30H24Cl2FeN6
摩爾質量	595.3 g·mol−1
外觀	紅色固體
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

氯化三(2,2'-聯吡啶)合鐵(II)是一種配位化合物，化學式為[Fe(C₁₀H₈N₂)₃]Cl₂，可簡寫為[Fe(bipy)₃]Cl₂，為紅色固體。由於primogenic效應，其激發態遲豫太快，相比於氯化三(聯吡啶)合釕(II)來說，它難以作為光敏劑（英語：Photosensitizer）有所應用。

它可由2,2'-聯吡啶和氯化亞鐵在水、乙腈、乙醇或1,2-二氯乙烷中反應製得。^[1]它在升華裝置內減壓下於80 °C加熱，可以得到深藍色的FeCl₂(bipy)₂。^[2]

參考文獻[編輯]

^ Avdeeva, Varvara V.; Vologzhanina, Anna V.; Goeva, Lyudmila V.; Malinina, Elena A.; Kuznetsov, Nikolay T. Boron Cluster Anions [B_nH_n]^2– (n = 10, 12) in Reactions of Iron(II) and Iron(III) Complexation with 2, 2′‐Bipyridyl and 1, 10‐Phenanthroline. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2014-07-09, 640 (11): 2149–2160. ISSN 0044-2313. doi:10.1002/zaac.201400137.
^ Yang, Ping; Chan, Bryan C. K.; Baird, Michael C. Is FeEt₂(2,2‘-dipyridyl)₂ a Ziegler Catalyst for Polymerization of the Polar Monomer Acrylonitrile?. Organometallics (American Chemical Society (ACS)). 2004-04-22, 23 (11): 2752–2761. ISSN 0276-7333. doi:10.1021/om0499613.

[1] Avdeeva, Varvara V.; Vologzhanina, Anna V.; Goeva, Lyudmila V.; Malinina, Elena A.; Kuznetsov, Nikolay T. Boron Cluster Anions [B_nH_n]^2– (n = 10, 12) in Reactions of Iron(II) and Iron(III) Complexation with 2, 2′‐Bipyridyl and 1, 10‐Phenanthroline. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2014-07-09, 640 (11): 2149–2160. ISSN 0044-2313. doi:10.1002/zaac.201400137.

[2] Yang, Ping; Chan, Bryan C. K.; Baird, Michael C. Is FeEt₂(2,2‘-dipyridyl)₂ a Ziegler Catalyst for Polymerization of the Polar Monomer Acrylonitrile?. Organometallics (American Chemical Society (ACS)). 2004-04-22, 23 (11): 2752–2761. ISSN 0276-7333. doi:10.1021/om0499613.

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