1,7-二溴庚烷 是一種有機化合物 ,化學式為C7 H14 Br2 。它可由1,7-庚二醇 和三溴化磷 在乙醚 重反應得到,[4] 或和氫溴酸 在相轉移催化劑的存在下反應製得。[5] 它具有鹵代烴(溴代烴)的通性,如在碳酸鉀 的存在下和4-巰基苯酚 反應,得到1,7-二(4-羥基苯硫基)庚烷。[6] 它在丙酮 中和碘化鈉 反應,可以得到1,7-二碘庚烷。[7]
參考文獻 [ 編輯 ]
^ Muller, Adolf; Vanc, Wenzel. Multimembered cyclic compounds. XII. Formation of ω,ω'-oxidoalkanes and ω,ω'-dibromodialkyl ethers from diprimary glycols and hydrogen bromide. Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen , 1944, 77B. 669-675. ISSN: 0365-9488.
^ William P. Hall, E. Emmet Reid. A Series of α,ι-Dimercaptans 1 . Journal of the American Chemical Society. 1943-08, 65 (8): 1466–1468 [2020-11-28 ] . ISSN 0002-7863 . doi:10.1021/ja01248a008 . (原始內容 存檔於2020-12-10) (英語) .
^ Gordon G. Cash, Suzanne Hartigan, Jay Tunkel. Normal boiling points of haloalkanes from electrotopological state indices . Toxicological & Environmental Chemistry. 2008-11, 90 (6): 1073–1089 [2020-11-28 ] . ISSN 0277-2248 . doi:10.1080/02772240701862116 (英語) .
^ Ben-Sasson, Shmuel; Gross, Einav. Compounds and uses for the treatment and prevention of diseases and conditions associate with or aggravated by impaired mitophagy. 2019. WO 2019175873 A1.
^ Guoqin Hu, Hua Li, Juan Liu, Jiang Zhu. Preparation of Supported CTAB/MCM-41 and CTAB-Nafion/MCM-41 Mesoporous Molecular Sieve and Their Use in the Brominating Reaction . Journal of the Korean Chemical Society. 2011-08-20, 55 (4): 691–696 [2020-11-28 ] . ISSN 1017-2548 . doi:10.5012/jkcs.2011.55.4.691 . (原始內容存檔 於2018-06-04) (英語) .
^ Yuki Arakawa, Kenta Komatsu, Satoyoshi Inui, Hideto Tsuji. Thioether-linked liquid crystal dimers and trimers: The twist-bend nematic phase . Journal of Molecular Structure. 2020-01, 1199 : 126913 [2020-11-28 ] . doi:10.1016/j.molstruc.2019.126913 (英語) .
^ Manuel Petroselli, Venkatachalam Angamuthu, Faiz-Ur Rahman, Xinluo Zhao, Yang Yu, Julius Rebek. Radical Reactions in Cavitands Unveil the Effects of Affinity on Dynamic Supramolecular Systems . Journal of the American Chemical Society. 2020-02-05, 142 (5): 2396–2403 [2020-11-28 ] . ISSN 0002-7863 . doi:10.1021/jacs.9b11595 . (原始內容 存檔於2022-04-19) (英語) .