钨酸锌

钨酸锌是一种无机化合物，化学式为ZnWO₄，它在自然界以和铁共生的钨锌矿（德语：Sanmartinit）的形式存在。它可由氯化锌或硝酸锌和钨酸钠在水溶液中反应得到。^[1]^[2]^[3]

\mathrm {Na_{2}WO_{4}+ZnCl_{2}\longrightarrow ZnWO_{4}\downarrow +\ 2\ NaCl}

它和稀土单钨酸盐（RE₂O₂WO₄）在高温加热反应，可以结晶出ZnRE₄W₃O₁₆（RE=Y, Nd, Sm, Eu, Gd, Dy, Ho, Er, Lu）。^[4]

参考文献[编辑]

^ Eric da Cruz Severo, Ederson Rossi Abaide, Chayene Gonçalves Anchieta, Vitória Segabinazzi Foletto, Caroline Trevisan Weber, Tais Bisognin Garlet, Gabriela Carvalho Collazzo, Marcio Antonio Mazutti, André Gündel, Raquel Cristine Kuhn, Edson Luiz Foletto: Preparation of Zinc Tungstate (ZnWO₄) Particles by Solvo-hydrothermal Technique and their Application as Support for Inulinase Immobilization. In: Materials Research. 2016, S. 0, doi:10.1590/1980-5373-MR-2015-0100.
^ Mehdi Rahimi-Nasrabadi, Seied Mahdi Pourmortazavi, Mohammad Reza Ganjali, Seiedeh Somayyeh Hajimirsadeghi, Mir Mahdi Zahedi: Electrosynthesis and characterization of zinc tungstate nanoparticles. In: Journal of Molecular Structure. 1047, 2013, S. 31, doi:10.1016/j.molstruc.2013.04.050.
^ Saman Rahnamaeiyan, Mahdi Nasiri, Amin Alborzi, S. Mahdi Tabatabaei: Sonochemical synthesis and characterization of zinc tungstate nanoparticles and investigation of its photocatalyst application. In: Journal of Materials Science: Materials in Electronics. 27, 2016, S. 1113, doi:10.1007/s10854-015-3859-5.
^ E. Tomaszewicz. Synthesis and some properties of new zinc and rare-earth metal tungstates ZnRE4W3O16. Solid State Sciences. 2006-05, 8 (5): 508–512 [2023-02-13]. doi:10.1016/j.solidstatesciences.2005.12.009. （原始内容存档于2018-06-28）（英语）.