氯化［吡啶-2,6-二(2,1-亞苯基)］金

氯化［吡啶-2,6-二(2,1-亞苯基)］金
	IUPAC名; (SP-4-2)-Chloro[(2,6-pyridinediyl-κN)di(2,1-phenylene-κC)]gold
識別
CAS號	211680-78-3
SMILES	c1cccc(c2cccc(n2)c3cccc[cH-]3)[cH-]1.[Au+3].[Cl-];
性質
化學式	C17H11AuClN
摩爾質量	461.7 g·mol−1
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

氯化[吡啶-2,6-二(2,1-亞苯基)]金是一種配位化合物，化學式為C₁₇H₁₁AuClN，它可由氯化[2-(6-苯基-2-吡啶基)苯基]汞和氯金酸鉀（KAuCl₄）在乙腈中回流反應得到。^[1]它和三氟乙酸銀在二氯甲烷中反應，氯可以被三氟乙酸根取代。^[1]它在室溫下和1,3,5-三氮雜-7-磷雜金剛烷（PTA）反應，得到[C₁₇H₁₁NAu-PTA]PF₆。^[2]在相應的反應條件下，也能得到含有新的Au-C鍵的有機金化合物。^[3]^[4]

參考文獻[編輯]

^ ^1.0 ^1.1 Wai-Pong To, Glenna So Ming Tong, Chi-Wah Cheung, Chen Yang, Dongling Zhou, Chi-Ming Che. Luminescent Cyclometalated Gold(III) Alkyl Complexes: Photophysical and Photochemical Properties. Inorganic Chemistry. 2017-05, 56 (9): 5046–5059 [2019-10-15]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.7b00180 （英語）.
^ Sophie Jürgens, Valeria Scalcon, Natalia Estrada-Ortiz, Alessandra Folda, Federica Tonolo, Christian Jandl, Duncan L. Browne, Maria Pia Rigobello, Fritz E. Kühn, Angela Casini. Exploring the C^N^C theme: Synthesis and biological properties of tridentate cyclometalated gold(III) complexes. Bioorganic & Medicinal Chemistry. 2017-10, 25 (20): 5452–5460 [2019-10-15]. doi:10.1016/j.bmc.2017.08.001. （原始內容存檔於2019-08-26）（英語）.
^ Vonika Ka-Man Au, Keith Man-Chung Wong, Nianyong Zhu, Vivian Wing-Wah Yam. Luminescent Cyclometalated N -Heterocyclic Carbene-Containing Organogold(III) Complexes: Synthesis, Characterization, Electrochemistry, and Photophysical Studies. Journal of the American Chemical Society. 2009-07, 131 (25): 9076–9085 [2019-10-15]. ISSN 0002-7863. doi:10.1021/ja9027692 （英語）.
^ Vonika Ka-Man Au, Nianyong Zhu, Vivian Wing-Wah Yam. Luminescent Metallogels of Bis-Cyclometalated Alkynylgold(III) Complexes. Inorganic Chemistry. 2013-01-18, 52 (2): 558–567 [2019-10-15]. ISSN 0020-1669. doi:10.1021/ic3007519. （原始內容存檔於2020-10-30）（英語）.

[To-1] 1.0 ^1.1 Wai-Pong To, Glenna So Ming Tong, Chi-Wah Cheung, Chen Yang, Dongling Zhou, Chi-Ming Che. Luminescent Cyclometalated Gold(III) Alkyl Complexes: Photophysical and Photochemical Properties. Inorganic Chemistry. 2017-05, 56 (9): 5046–5059 [2019-10-15]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.7b00180 （英語）.

[2] Sophie Jürgens, Valeria Scalcon, Natalia Estrada-Ortiz, Alessandra Folda, Federica Tonolo, Christian Jandl, Duncan L. Browne, Maria Pia Rigobello, Fritz E. Kühn, Angela Casini. Exploring the C^N^C theme: Synthesis and biological properties of tridentate cyclometalated gold(III) complexes. Bioorganic & Medicinal Chemistry. 2017-10, 25 (20): 5452–5460 [2019-10-15]. doi:10.1016/j.bmc.2017.08.001. （原始內容存檔於2019-08-26）（英語）.

[3] Vonika Ka-Man Au, Keith Man-Chung Wong, Nianyong Zhu, Vivian Wing-Wah Yam. Luminescent Cyclometalated N -Heterocyclic Carbene-Containing Organogold(III) Complexes: Synthesis, Characterization, Electrochemistry, and Photophysical Studies. Journal of the American Chemical Society. 2009-07, 131 (25): 9076–9085 [2019-10-15]. ISSN 0002-7863. doi:10.1021/ja9027692 （英語）.

[4] Vonika Ka-Man Au, Nianyong Zhu, Vivian Wing-Wah Yam. Luminescent Metallogels of Bis-Cyclometalated Alkynylgold(III) Complexes. Inorganic Chemistry. 2013-01-18, 52 (2): 558–567 [2019-10-15]. ISSN 0020-1669. doi:10.1021/ic3007519. （原始內容存檔於2020-10-30）（英語）.

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