乙酰丙酮铽

乙酰丙酮铽
识别
CAS号	14284-95-8
性质
化学式	C15H21O6Tb
摩尔质量	456.25 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

乙酰丙酮铽是一种配位化合物，化学式为Tb(C₅H₇O₂)₃，或简写为Tb(acac)₃。它可由氨水、乙酰丙酮和硝酸铽反应制得：^[1]

3 NH₃ + 3 Hacac + Tb(NO₃)₃ → Tb(acac)₃ + 3 NH₄NO₃

它和5-[(2-噻吩亚甲基)氨基]-8-羟基喹啉（L）在乙腈/二氯甲烷溶液中加热反应，可以得到浅黄色[Tb(acac)₄(L)₆(μ3-OH)₂]·CH₃CN晶体。^[2]它可用于一些光学材料的制备。^[3]^[4]^[5]

参考文献[编辑]

^ Anees A. Ansari, Joselito P. Labis. One-pot synthesis and photoluminescence properties of luminescent functionalized mesoporous SiO2@Tb(OH)3 core–shell nanospheres. Journal of Materials Chemistry. 2012, 22 (32): 16649 [2021-09-20]. ISSN 0959-9428. doi:10.1039/c2jm33583b （英语）.
^ Wen-Min Wang, Lei Huai, Xi-Wen Wang, Kai-Jun Jiang, Hai-Yun Shen, Hong-Ling Gao, Ming Fang, Jian-Zhong Cui. Structures, magnetic refrigeration and single molecule-magnet behavior of five rhombus-shaped tetranuclear Ln( iii )-based clusters. New Journal of Chemistry. 2020, 44 (25): 10266–10274 [2021-09-20]. ISSN 1144-0546. doi:10.1039/D0NJ01969K （英语）.
^ Rui Jia, Ting Gao, Yu Yang, Wenbin Sun, Ruoxi Chen, Pengfei Yan, Guangfeng Hou. Luminescence of Salen Lanthanide Bimetallic Complexes: Dual Emission and Energy Transfer: Luminescence of Salen Lanthanide Bimetallic Complexes. Zeitschrift für anorganische und allgemeine Chemie. 2015-09, 641 (11): 1974–n/a [2021-09-20]. doi:10.1002/zaac.201500138. （原始内容存档于2021-09-16）（英语）.
^ Gaël Zucchi, Taewoo Jeon, Denis Tondelier, Dmitry Aldakov, Pierre Thuéry, Michel Ephritikhine, Bernard Geffroy. White electroluminescence of lanthanide complexes resulting from exciplex formation. Journal of Materials Chemistry. 2010, 20 (11): 2114 [2021-09-20]. ISSN 0959-9428. doi:10.1039/b921740a （英语）.
^ Anna M. Kaczmarek, Ying‐Ya Liu, Mariusz K. Kaczmarek, Hengshuo Liu, Flavia Artizzu, Luís D. Carlos, Pascal Van Der Voort. Developing Luminescent Ratiometric Thermometers Based on a Covalent Organic Framework (COF). Angewandte Chemie International Edition. 2020-01-27, 59 (5): 1932–1940 [2021-09-20]. ISSN 1433-7851. doi:10.1002/anie.201913983. （原始内容存档于2021-09-16）（英语）.

[1] Anees A. Ansari, Joselito P. Labis. One-pot synthesis and photoluminescence properties of luminescent functionalized mesoporous SiO2@Tb(OH)3 core–shell nanospheres. Journal of Materials Chemistry. 2012, 22 (32): 16649 [2021-09-20]. ISSN 0959-9428. doi:10.1039/c2jm33583b （英语）.

[2] Wen-Min Wang, Lei Huai, Xi-Wen Wang, Kai-Jun Jiang, Hai-Yun Shen, Hong-Ling Gao, Ming Fang, Jian-Zhong Cui. Structures, magnetic refrigeration and single molecule-magnet behavior of five rhombus-shaped tetranuclear Ln( iii )-based clusters. New Journal of Chemistry. 2020, 44 (25): 10266–10274 [2021-09-20]. ISSN 1144-0546. doi:10.1039/D0NJ01969K （英语）.

[3] Rui Jia, Ting Gao, Yu Yang, Wenbin Sun, Ruoxi Chen, Pengfei Yan, Guangfeng Hou. Luminescence of Salen Lanthanide Bimetallic Complexes: Dual Emission and Energy Transfer: Luminescence of Salen Lanthanide Bimetallic Complexes. Zeitschrift für anorganische und allgemeine Chemie. 2015-09, 641 (11): 1974–n/a [2021-09-20]. doi:10.1002/zaac.201500138. （原始内容存档于2021-09-16）（英语）.

[4] Gaël Zucchi, Taewoo Jeon, Denis Tondelier, Dmitry Aldakov, Pierre Thuéry, Michel Ephritikhine, Bernard Geffroy. White electroluminescence of lanthanide complexes resulting from exciplex formation. Journal of Materials Chemistry. 2010, 20 (11): 2114 [2021-09-20]. ISSN 0959-9428. doi:10.1039/b921740a （英语）.

[5] Anna M. Kaczmarek, Ying‐Ya Liu, Mariusz K. Kaczmarek, Hengshuo Liu, Flavia Artizzu, Luís D. Carlos, Pascal Van Der Voort. Developing Luminescent Ratiometric Thermometers Based on a Covalent Organic Framework (COF). Angewandte Chemie International Edition. 2020-01-27, 59 (5): 1932–1940 [2021-09-20]. ISSN 1433-7851. doi:10.1002/anie.201913983. （原始内容存档于2021-09-16）（英语）.

[1]

[2]

[3]

[4]

[5]