乙酰丙酮鋱

乙酰丙酮鋱
識別
CAS號	14284-95-8
性質
化學式	C15H21O6Tb
摩爾質量	456.25 g·mol−1
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

乙酰丙酮鋱是一種配位化合物，化學式為Tb(C₅H₇O₂)₃，或簡寫為Tb(acac)₃。它可由氨水、乙酰丙酮和硝酸鋱反應製得：^[1]

3 NH₃ + 3 Hacac + Tb(NO₃)₃ → Tb(acac)₃ + 3 NH₄NO₃

它和5-[(2-噻吩亞甲基)氨基]-8-羥基喹啉（L）在乙腈/二氯甲烷溶液中加熱反應，可以得到淺黃色[Tb(acac)₄(L)₆(μ3-OH)₂]·CH₃CN晶體。^[2]它可用於一些光學材料的製備。^[3]^[4]^[5]

參考文獻[編輯]

^ Anees A. Ansari, Joselito P. Labis. One-pot synthesis and photoluminescence properties of luminescent functionalized mesoporous SiO2@Tb(OH)3 core–shell nanospheres. Journal of Materials Chemistry. 2012, 22 (32): 16649 [2021-09-20]. ISSN 0959-9428. doi:10.1039/c2jm33583b （英語）.
^ Wen-Min Wang, Lei Huai, Xi-Wen Wang, Kai-Jun Jiang, Hai-Yun Shen, Hong-Ling Gao, Ming Fang, Jian-Zhong Cui. Structures, magnetic refrigeration and single molecule-magnet behavior of five rhombus-shaped tetranuclear Ln( iii )-based clusters. New Journal of Chemistry. 2020, 44 (25): 10266–10274 [2021-09-20]. ISSN 1144-0546. doi:10.1039/D0NJ01969K （英語）.
^ Rui Jia, Ting Gao, Yu Yang, Wenbin Sun, Ruoxi Chen, Pengfei Yan, Guangfeng Hou. Luminescence of Salen Lanthanide Bimetallic Complexes: Dual Emission and Energy Transfer: Luminescence of Salen Lanthanide Bimetallic Complexes. Zeitschrift für anorganische und allgemeine Chemie. 2015-09, 641 (11): 1974–n/a [2021-09-20]. doi:10.1002/zaac.201500138. （原始內容存檔於2021-09-16）（英語）.
^ Gaël Zucchi, Taewoo Jeon, Denis Tondelier, Dmitry Aldakov, Pierre Thuéry, Michel Ephritikhine, Bernard Geffroy. White electroluminescence of lanthanide complexes resulting from exciplex formation. Journal of Materials Chemistry. 2010, 20 (11): 2114 [2021-09-20]. ISSN 0959-9428. doi:10.1039/b921740a （英語）.
^ Anna M. Kaczmarek, Ying‐Ya Liu, Mariusz K. Kaczmarek, Hengshuo Liu, Flavia Artizzu, Luís D. Carlos, Pascal Van Der Voort. Developing Luminescent Ratiometric Thermometers Based on a Covalent Organic Framework (COF). Angewandte Chemie International Edition. 2020-01-27, 59 (5): 1932–1940 [2021-09-20]. ISSN 1433-7851. doi:10.1002/anie.201913983. （原始內容存檔於2021-09-16）（英語）.

[1] Anees A. Ansari, Joselito P. Labis. One-pot synthesis and photoluminescence properties of luminescent functionalized mesoporous SiO2@Tb(OH)3 core–shell nanospheres. Journal of Materials Chemistry. 2012, 22 (32): 16649 [2021-09-20]. ISSN 0959-9428. doi:10.1039/c2jm33583b （英語）.

[2] Wen-Min Wang, Lei Huai, Xi-Wen Wang, Kai-Jun Jiang, Hai-Yun Shen, Hong-Ling Gao, Ming Fang, Jian-Zhong Cui. Structures, magnetic refrigeration and single molecule-magnet behavior of five rhombus-shaped tetranuclear Ln( iii )-based clusters. New Journal of Chemistry. 2020, 44 (25): 10266–10274 [2021-09-20]. ISSN 1144-0546. doi:10.1039/D0NJ01969K （英語）.

[3] Rui Jia, Ting Gao, Yu Yang, Wenbin Sun, Ruoxi Chen, Pengfei Yan, Guangfeng Hou. Luminescence of Salen Lanthanide Bimetallic Complexes: Dual Emission and Energy Transfer: Luminescence of Salen Lanthanide Bimetallic Complexes. Zeitschrift für anorganische und allgemeine Chemie. 2015-09, 641 (11): 1974–n/a [2021-09-20]. doi:10.1002/zaac.201500138. （原始內容存檔於2021-09-16）（英語）.

[4] Gaël Zucchi, Taewoo Jeon, Denis Tondelier, Dmitry Aldakov, Pierre Thuéry, Michel Ephritikhine, Bernard Geffroy. White electroluminescence of lanthanide complexes resulting from exciplex formation. Journal of Materials Chemistry. 2010, 20 (11): 2114 [2021-09-20]. ISSN 0959-9428. doi:10.1039/b921740a （英語）.

[5] Anna M. Kaczmarek, Ying‐Ya Liu, Mariusz K. Kaczmarek, Hengshuo Liu, Flavia Artizzu, Luís D. Carlos, Pascal Van Der Voort. Developing Luminescent Ratiometric Thermometers Based on a Covalent Organic Framework (COF). Angewandte Chemie International Edition. 2020-01-27, 59 (5): 1932–1940 [2021-09-20]. ISSN 1433-7851. doi:10.1002/anie.201913983. （原始內容存檔於2021-09-16）（英語）.

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